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What is the order of decreasing ionic radius?A.     S2− > Cl− > Al3+ > Mg2+B.     Cl− > S2− > Al3+ > Mg2+C.     S2− > Cl− > Mg2+ > Al3+D.     Mg2+ > Al3+ > Cl− > S2−

Question

What is the order of decreasing ionic radius?A.     S2− > Cl− > Al3+ > Mg2+B.     Cl− > S2− > Al3+ > Mg2+C.     S2− > Cl− > Mg2+ > Al3+D.     Mg2+ > Al3+ > Cl− > S2−

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Solution

The order of decreasing ionic radius is determined by the number of electrons and the effective nuclear charge.

  1. S2-: This ion has the most electrons (18) and a relatively low effective nuclear charge due to its position in the third period of the periodic table. This results in a larger ionic radius.

  2. Cl-: This ion has fewer electrons (18) than S2-, but it is in the same period. However, it has a higher effective nuclear charge, which pulls the electrons closer to the nucleus, resulting in a smaller ionic radius than S2-.

  3. Al3+: This ion has fewer electrons (10) and is in the third period. It has a higher effective nuclear charge than both S2- and Cl-, which pulls the electrons even closer to the nucleus, resulting in a smaller ionic radius.

  4. Mg2+: This ion has the same number of electrons (10) as Al3+, but it is in the second period. It has a higher effective nuclear charge than Al3+, which pulls the electrons even closer to the nucleus, resulting in the smallest ionic radius.

So, the correct order of decreasing ionic radius is S2- > Cl- > Al3+ > Mg2+, which corresponds to option A.

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Similar Questions

the order of increasing radius in ionic solution

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3. Which of the following has the largest ionic radius?Ca2+K+Cl-Ar

Deduce the correct order for the following elements in order of decreasing atomic radius: S, K, Cl and F.F > Cl > S > KK > F > Cl > SK > S > Cl > FF > Cl > K > S

Deduce which of the following species has the largest ionic radius.S2−F−Al3+Mg2+

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