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If it took 976seconds for a sample of HCN to effuse, for which of the following would it require 2150seconds for the same number of moles to effuse?CH4NeNH3ArXeChemistry and Chemical ReactivityKotz and Treichel;Thomson PublishingChapter 12.7Lecture Help Main PageFeedback to Dr Van BramerFeedback to George Wiger

Question

If it took 976seconds for a sample of HCN to effuse, for which of the following would it require 2150seconds for the same number of moles to effuse?CH4NeNH3ArXeChemistry and Chemical ReactivityKotz and Treichel;Thomson PublishingChapter 12.7Lecture Help Main PageFeedback to Dr Van BramerFeedback to George Wiger

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Solution

The question is asking to apply Graham's law of effusion, which states that the rate of effusion of a gas is inversely proportional to the square root of its molar mass.

The formula for Graham's law of effusion is:

Rate1/Rate2 = sqrt(M2/M1)

Given that it took 976 seconds for HCN to effuse, we can find the rate of effusion for HCN as:

Rate1 = 1/976 moles/second

We are asked to find the gas that would take 2150 seconds to effuse the same number of moles, so the rate of effusion for this unknown gas is:

Rate2 = 1/2150 moles/second

Substituting these values into Graham's law of effusion gives:

1/976 / 1/2150 = sqrt(M2/M1)

Solving for M2 (the molar mass of the unknown gas) gives:

M2 = M1 * (2150/976)^2

The molar mass of HCN (M1) is approximately 27.03 g/mol. Substituting this value in gives:

M2 = 27.03 * (2150/976)^2 = 79.9 g/mol

Looking at the molar masses of the given gases, the one that is closest to 79.9 g/mol is Ar (argon), with a molar mass of approximately 39.95 g/mol. Therefore, the gas that would take 2150 seconds to effuse the same number of moles as HCN is Ar (argon).

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