Which of the following combinations can be used to make a buffer? (Assume equal volumes are used.)A 0.50 M HF and 0.20 M NaFB 0.50 M HF and 0.50 M NaOHC 0.50 M HF and 0.50 M HClD 0.50 M HCl and 0.50 M NaF
Question
Which of the following combinations can be used to make a buffer? (Assume equal volumes are used.)A 0.50 M HF and 0.20 M NaFB 0.50 M HF and 0.50 M NaOHC 0.50 M HF and 0.50 M HClD 0.50 M HCl and 0.50 M NaF
Solution
A buffer solution is made up of a weak acid and its conjugate base or a weak base and its conjugate acid.
A. 0.50 M HF and 0.20 M NaF: This is a combination of a weak acid (HF) and its conjugate base (F- from NaF). So, this can be used to make a buffer.
B. 0.50 M HF and 0.50 M NaOH: This is a combination of a weak acid (HF) and a strong base (OH- from NaOH). This cannot be used to make a buffer because the strong base will completely neutralize the weak acid.
C. 0.50 M HF and 0.50 M HCl: This is a combination of a weak acid (HF) and a strong acid (HCl). This cannot be used to make a buffer because the strong acid will dominate the pH of the solution.
D. 0.50 M HCl and 0.50 M NaF: This is a combination of a strong acid (HCl) and a conjugate base (F- from NaF). This cannot be used to make a buffer because the strong acid will completely neutralize the conjugate base.
So, the only combination that can be used to make a buffer is A: 0.50 M HF and 0.20 M NaF.
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