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Explain the trend in the melting points of the oxides down Group 2.

Question

Explain the trend in the melting points of the oxides down Group 2.

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Solution

The trend in the melting points of the oxides down Group 2 can be explained as follows:

  1. Group 2 elements include Beryllium (Be), Magnesium (Mg), Calcium (Ca), Strontium (Sr), Barium (Ba), and Radium (Ra). The oxides of these elements are BeO, MgO, CaO, SrO, BaO, and RaO respectively.

  2. As we move down Group 2, the size of the atoms increases. This is due to the addition of electron shells.

  3. The melting point of an oxide is determined by the strength of the bonds within the compound. The stronger the bonds, the higher the melting point.

  4. In Group 2 oxides, the bonding is ionic, and the strength of an ionic bond is determined by the charge on the ions and the size of the ions.

  5. The charge on the ions in Group 2 oxides is the same (+2 for the metal ion and -2 for the oxide ion), but the size of the metal ion increases down the group.

  6. As the size of the ion increases, the distance between the positive and negative charges also increases. This results in a decrease in the strength of the ionic bond.

  7. Therefore, as we move down Group 2, the melting points of the oxides decrease due to the weakening of the ionic bonds caused by the increasing size of the metal ions.

  8. However, there is an anomaly at magnesium oxide, which has a much higher melting point than the rest of the group. This is due to its structure, which is a close-packed array of ions, leading to strong ionic bonds in all directions and hence a high melting point.

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