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Which of the following species has highest oxidation number of 'Cl' ?Cl2HClO3HClO4HCl

Question

Which of the following species has highest oxidation number of 'Cl' ?Cl2HClO3HClO4HCl

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Solution

The oxidation number of Cl in different species is as follows:

  1. Cl2: In this molecule, Cl is in its elemental form, so its oxidation number is 0.

  2. HCl: In this molecule, Cl has an oxidation number of -1. This is because hydrogen usually has an oxidation number of +1, and the total oxidation numbers in a neutral molecule must add up to zero.

  3. HClO3: In this molecule, oxygen has an oxidation number of -2 and hydrogen has an oxidation number of +1. Since the molecule is neutral, the sum of the oxidation numbers must be zero. Therefore, the oxidation number of Cl in HClO3 is +5.

  4. HClO4: In this molecule, oxygen has an oxidation number of -2 and hydrogen has an oxidation number of +1. Since the molecule is neutral, the sum of the oxidation numbers must be zero. Therefore, the oxidation number of Cl in HClO4 is +7.

So, the species with the highest oxidation number of Cl is HClO4.

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