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Hydrochloric acid (Mr = 36.5) reacts with calcium carbonate (Mr = 100) to make calcium chloride (Mr = 75.5), water (Mr = 18) and carbon dioxide (Mr = 44), according to the following equation:CaCO3 + 2HCl → CaCl2 + H2O + CO2At STP, 5 g of calcium carbonate reacts and produces 330 cm3 of carbon dioxide. What is the % yield of carbon dioxide in this reaction?Molar volume of a gas at STP = 22.7 dm3 = 22700 cm370.9%0.29%33.0%29.1%

Question

Hydrochloric acid (Mr = 36.5) reacts with calcium carbonate (Mr = 100) to make calcium chloride (Mr = 75.5), water (Mr = 18) and carbon dioxide (Mr = 44), according to the following equation:CaCO3 + 2HCl → CaCl2 + H2O + CO2At STP, 5 g of calcium carbonate reacts and produces 330 cm3 of carbon dioxide. What is the % yield of carbon dioxide in this reaction?Molar volume of a gas at STP = 22.7 dm3 = 22700 cm370.9%0.29%33.0%29.1%

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Solution

To solve this problem, we need to follow these steps:

  1. Calculate the number of moles of calcium carbonate (CaCO3) used: The molar mass of CaCO3 is 100 g/mol. So, 5 g of CaCO3 is 5/100 = 0.05 mol.

  2. According to the balanced chemical equation, one mole of CaCO3 produces one mole of CO2. So, 0.05 mol of CaCO3 should theoretically produce 0.05 mol of CO2.

  3. Calculate the theoretical volume of CO2 produced: At STP, one mole of any gas occupies 22.7 dm3 (or 22700 cm3). So, 0.05 mol of CO2 should occupy 0.05 * 22700 = 1135 cm3.

  4. Calculate the percentage yield: The actual volume of CO2 produced is given as 330 cm3. So, the percentage yield = (actual yield/theoretical yield) * 100 = (330/1135) * 100 = 29.1%.

So, the % yield of carbon dioxide in this reaction is 29.1%.

This problem has been solved

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