number of isomers possible for [Co(en)²Cl(NO²)]Cl are
Question
number of isomers possible for [Co(en)²Cl(NO²)]Cl are
Solution
To determine the number of isomers possible for [Co(en)²Cl(NO²)]Cl, we need to analyze the different ways in which the ligands can be arranged around the central cobalt (Co) atom.
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Start by identifying the ligands present in the complex:
- en: ethylenediamine
- Cl: chloride
- NO²: nitrite
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Determine the coordination number of the central Co atom. In this case, it is 6 because there are six ligands attached to the Co atom.
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Consider the different possible arrangements of the ligands around the central Co atom. The ligands can be arranged in different ways, resulting in different isomers. The possible arrangements include:
a. Cis isomers: In cis isomers, two similar ligands are adjacent to each other.
- [Co(en)²Cl(NO²)]Cl (cis-1)
- [Co(NO²)Cl(en)²]Cl (cis-2)
b. Trans isomers: In trans isomers, two similar ligands are opposite to each other.
- [Co(en)²Cl(NO²)]Cl (trans-1)
- [Co(NO²)Cl(en)²]Cl (trans-2)
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Count the total number of isomers. In this case, we have four possible isomers: cis-1, cis-2, trans-1, and trans-2.
Therefore, the number of isomers possible for [Co(en)²Cl(NO²)]Cl is four.
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