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Rank the effective nuclear charge Z* experienced by a valence electron in each of these atoms:

Question

Rank the effective nuclear charge Z* experienced by a valence electron in each of these atoms:

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Solution

Sure, I can help with that. To rank the effective nuclear charge Z Z^* experienced by a valence electron in each of these atoms, follow these steps:

  1. Identify the Atomic Number (Z): Determine the number of protons in the nucleus for each atom. This is the atomic number (Z).

  2. Determine the Number of Core Electrons (S): Identify the number of electrons that are not in the valence shell. These are the core electrons.

  3. Calculate the Effective Nuclear Charge (Z):* Use the formula Z=ZS Z^* = Z - S , where Z Z is the atomic number and S S is the number of core electrons.

  4. Compare the Effective Nuclear Charges: Rank the atoms based on the calculated Z Z^* values.

Let's apply these steps to a set of example atoms: Sodium (Na), Magnesium (Mg), and Aluminum (Al).

  1. Identify the Atomic Number (Z):

    • Sodium (Na): Z=11 Z = 11
    • Magnesium (Mg): Z=12 Z = 12
    • Aluminum (Al): Z=13 Z = 13
  2. Determine the Number of Core Electrons (S):

    • Sodium (Na): Core electrons = 10 (1s² 2s² 2p⁶)
    • Magnesium (Mg): Core electrons = 10 (1s² 2s² 2p⁶)
    • Aluminum (Al): Core electrons = 10 (1s² 2s² 2p⁶)
  3. Calculate the Effective Nuclear Charge (Z):*

    • Sodium (Na): Z=1110=1 Z^* = 11 - 10 = 1
    • Magnesium (Mg): Z=1210=2 Z^* = 12 - 10 = 2
    • Aluminum (Al): Z=1310=3 Z^* = 13 - 10 = 3
  4. Compare the Effective Nuclear Charges:

    • Sodium (Na): Z=1 Z^* = 1
    • Magnesium (Mg): Z=2 Z^* = 2
    • Aluminum (Al): Z=3 Z^* = 3

Ranking:

  • Aluminum (Al) > Magnesium (Mg) > Sodium (Na)

So, the effective nuclear charge Z Z^* experienced by a valence electron is highest in Aluminum (Al), followed by Magnesium (Mg), and lowest in Sodium (Na).

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