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Most of the sulfur used in the United States is chemically synthesized from hydrogen sulfide gas recovered from natural gas wells. In the first step of this synthesis, called the Claus process, hydrogen sulfide gas is reacted with dioxygen gas to produce gaseous sulfur dioxide and water.Suppose a chemical engineer studying a new catalyst for the Claus reaction finds that 620. liters per second of dioxygen are consumed when the reaction is run at 179.°C and the dioxygen is supplied at 0.82atm. Calculate the rate at which sulfur dioxide is being produced. Give your answer in kilograms per second. Round your answer to 2 significant digits.

Question

Most of the sulfur used in the United States is chemically synthesized from hydrogen sulfide gas recovered from natural gas wells. In the first step of this synthesis, called the Claus process, hydrogen sulfide gas is reacted with dioxygen gas to produce gaseous sulfur dioxide and water.Suppose a chemical engineer studying a new catalyst for the Claus reaction finds that 620. liters per second of dioxygen are consumed when the reaction is run at 179.°C and the dioxygen is supplied at 0.82atm. Calculate the rate at which sulfur dioxide is being produced. Give your answer in kilograms per second. Round your answer to 2 significant digits.

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Solution

To solve this problem, we need to follow these steps:

  1. Write the balanced chemical equation for the Claus process: 2H2S(g)+O2(g)2S(s)+2H2O(g) 2H_2S(g) + O_2(g) \rightarrow 2S(s) + 2H_2O(g)

  2. Use the ideal gas law to find the moles of dioxygen consumed per second: The ideal gas law is given by: PV=nRT PV = nRT Where:

    • P P is the pressure (0.82 atm)
    • V V is the volume (620 L)
    • R R is the ideal gas constant (0.0821 L·atm/(K·mol))
    • T T is the temperature in Kelvin (179°C + 273 = 452 K)

    Rearrange the ideal gas law to solve for n n (moles of O2 O_2 ): n=PVRT n = \frac{PV}{RT} n=(0.82 atm)(620 L)(0.0821 L\cdotpatm/(K\cdotpmol))(452 K) n = \frac{(0.82 \text{ atm})(620 \text{ L})}{(0.0821 \text{ L·atm/(K·mol)})(452 \text{ K})} n13.6 mol/s n \approx 13.6 \text{ mol/s}

  3. Determine the moles of sulfur dioxide produced per second: From the balanced equation, 1 mole of O2 O_2 produces 1 mole of SO2 SO_2 . Therefore, the moles of SO2 SO_2 produced per second is also 13.6 mol/s.

  4. Convert moles of sulfur dioxide to mass: The molar mass of SO2 SO_2 is: 32.07 g/mol (S)+2×16.00 g/mol (O)=64.07 g/mol 32.07 \text{ g/mol (S)} + 2 \times 16.00 \text{ g/mol (O)} = 64.07 \text{ g/mol}

    The mass of SO2 SO_2 produced per second is: 13.6 mol/s×64.07 g/mol=871.35 g/s 13.6 \text{ mol/s} \times 64.07 \text{ g/mol} = 871.35 \text{ g/s}

  5. Convert grams per second to kilograms per second: 871.35 g/s=0.87 kg/s 871.35 \text{ g/s} = 0.87 \text{ kg/s}

Therefore, the rate at which sulfur dioxide is being produced is approximately 0.87 kg/s 0.87 \text{ kg/s} .

This problem has been solved

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