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When equal molar amounts of the following sets of compounds are mixed in water, which will not form a buffer solution?Group of answer choicesCH3CO2H with LiCH3CO2KH2PO4 with K2HPO4HNO3 with LiNO3NH3 with NH4I

Question

When equal molar amounts of the following sets of compounds are mixed in water, which will not form a buffer solution?Group of answer choicesCH3CO2H with LiCH3CO2KH2PO4 with K2HPO4HNO3 with LiNO3NH3 with NH4I

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Solution

A buffer solution is formed by a weak acid and its conjugate base or a weak base and its conjugate acid.

  1. CH3CO2H with LiCH3CO2: This is a weak acid (acetic acid) and its conjugate base (acetate ion), so it will form a buffer solution.

  2. H2PO4 with K2HPO4: This is a weak acid (dihydrogen phosphate) and its conjugate base (hydrogen phosphate), so it will form a buffer solution.

  3. HNO3 with LiNO3: Nitric acid (HNO3) is a strong acid, not a weak acid, and its conjugate base is the nitrate ion (NO3-). Therefore, this pair will not form a buffer solution.

  4. NH3 with NH4I: This is a weak base (ammonia) and its conjugate acid (ammonium ion), so it will form a buffer solution.

So, the pair that will not form a buffer solution is HNO3 with LiNO3.

This problem has been solved

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