Multiplicity of C-C bond decreases with increase in s-character
Question
Multiplicity of C-C bond decreases with increase in s-character
Solution
The multiplicity of a C-C bond refers to the number of bonds between two carbon atoms. This can be a single bond, double bond, or triple bond. The s-character of a bond refers to the percentage of the bond's electron cloud that is derived from the s-orbital of the atom.
-
In a single bond (like in alkanes), the bond is sp3 hybridized, meaning it has 25% s-character and 75% p-character.
-
In a double bond (like in alkenes), the bond is sp2 hybridized, meaning it has 33% s-character and 67% p-character.
-
In a triple bond (like in alkynes), the bond is sp hybridized, meaning it has 50% s-character and 50% p-character.
As the s-character increases, the bond length decreases and the bond becomes stronger. This is because s-orbitals are closer to the nucleus and therefore lower in energy than p-orbitals, so a bond with more s-character is lower in energy (more stable) and shorter.
So, as the s-character increases from sp3 to sp2 to sp, the multiplicity of the C-C bond decreases from single to double to triple. This is because a bond with more s-character is stronger and shorter, so it can support more bonds (higher multiplicity).
In conclusion, the multiplicity of a C-C bond decreases with an increase in s-character.
Similar Questions
Assertion : HC ≡ C– is more stable than H2C = CH–Reason : HC ≡ C– has more s-character than H2C = CH–
The catenation tendency of C,Si and Ge is in the order Ge<Si<C. The bond energies (in kJ mol−1 ) of C−C,Si−Si and Ge−Ge bonds are respectively ;348,297,260297,348,260348,260,297260,297,348
In which reaction, C–C bond formation does not take place?
Use the information below to answer questions 28 to 30. Bond C is a 2-year semi-annual bond with a par value of R1000. It has a yield to maturity of 14% and a coupon rate of 10%. Bond C has a convexity of 19.303. Calculate the total effect of Bond C, if the yield to maturity increases by 1%.Select one:a.-1.54%b.1.94%c.-1.94%d.1.54%
char *_strchr(char *s, char c)
Upgrade your grade with Knowee
Get personalized homework help. Review tough concepts in more detail, or go deeper into your topic by exploring other relevant questions.