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Suppose 18.9g of iron(Ⅲ) chloride FeCl3 are dissolved in 830.mL of water. Find the composition of the resulting electrolyte solution.In particular, list the chemical symbols (including any charge) of each dissolved ion in the table below. List only one ion per row.Then, calculate the concentration of each ion in mEqL, and write the concentration in the second column of each row. Be sure you round your answers to the correct number of significant digits.

Question

Suppose 18.9g of iron(Ⅲ) chloride FeCl3 are dissolved in 830.mL of water. Find the composition of the resulting electrolyte solution.In particular, list the chemical symbols (including any charge) of each dissolved ion in the table below. List only one ion per row.Then, calculate the concentration of each ion in mEqL, and write the concentration in the second column of each row. Be sure you round your answers to the correct number of significant digits.

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Solution

First, let's identify the ions that will be present in the solution. When iron(III) chloride, or FeCl3, dissolves in water, it dissociates into its constituent ions: Fe3+ and Cl-.

Now, let's calculate the concentration of each ion in mEq/L.

  1. Calculate the number of moles of FeCl3: The molar mass of FeCl3 is approximately 162.2 g/mol. So, the number of moles of FeCl3 is given by: Moles = mass / molar mass = 18.9 g / 162.2 g/mol = 0.1165 mol

  2. Calculate the volume of the solution in liters: Volume = 830 mL = 0.830 L

  3. Calculate the concentration of Fe3+: Since each molecule of FeCl3 produces one Fe3+ ion, the concentration of Fe3+ is the same as the concentration of FeCl3. Concentration = moles / volume = 0.1165 mol / 0.830 L = 0.1404 mol/L

    To convert this to mEq/L, we multiply by the charge of the ion (3) and by 1000 (since 1 Eq = 1 mol of charge, and 1 mEq = 1/1000 Eq): Concentration = 0.1404 mol/L * 3 * 1000 = 421.2 mEq/L

  4. Calculate the concentration of Cl-: Each molecule of FeCl3 produces three Cl- ions, so the concentration of Cl- is three times the concentration of FeCl3. Concentration = 3 * 0.1165 mol / 0.830 L = 0.4212 mol/L

    To convert this to mEq/L, we multiply by the charge of the ion (1) and by 1000: Concentration = 0.4212 mol/L * 1 * 1000 = 421.2 mEq/L

So, the composition of the solution is as follows:

Ion Concentration (mEq/L)
Fe3+ 421.2
Cl- 1263.6

This problem has been solved

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