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Potassium manganate(VII) reacts with  potassium iodide. The change in oxidation number of manganese is from +7 to +2. What change has occurred to the iodide ions?

Question

Potassium manganate(VII) reacts with  potassium iodide. The change in oxidation number of manganese is from +7 to +2. What change has occurred to the iodide ions?

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Solution

In the reaction between potassium manganate(VII) and potassium iodide, the iodide ions are oxidized. This means that the oxidation number of iodine increases.

The oxidation number of iodine in iodide ions (I-) is -1. Since the manganese is reduced from +7 to +2 (a decrease of 5), the iodine must be oxidized by the same amount to maintain charge balance in the reaction.

Therefore, the oxidation number of iodine increases from -1 to +4. This is a change of +5, which matches the change in the manganese oxidation number.

So, the iodide ions have been oxidized in this reaction.

This problem has been solved

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