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What is the decreasing order of stability of the ions?I. CH3−C+H−CH3   II. CH3−C+H−OCH3III. CH3−C+H−COCH3

Question

What is the decreasing order of stability of the ions?I. CH3−C+H−CH3   II. CH3−C+H−OCH3III. CH3−C+H−COCH3

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Solution

The stability of carbocations is determined by the ability of the surrounding atoms or groups to donate electron density to the positively charged carbon. This is often referred to as +I effect or hyperconjugation.

The order of stability for the given carbocations can be determined as follows:

I. CH3−C+H−CH3: This is a secondary carbocation, where the positively charged carbon is surrounded by two methyl groups. These methyl groups can donate electron density to the positively charged carbon, stabilizing it.

II. CH3−C+H−OCH3: This is a secondary carbocation where one of the groups is a methoxy group (-OCH3). Oxygen is more electronegative than carbon, so it will not donate electron density as effectively as a carbon. However, it can still provide some stabilization through resonance.

III. CH3−C+H−COCH3: This is a secondary carbocation where one of the groups is a carbonyl group (-COCH3). The carbonyl group is electron withdrawing, which destabilizes the carbocation.

So, the order of stability is: I > II > III.

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