Sigma bond is stronger than pi bond. Give reason.
Question
Sigma bond is stronger than pi bond. Give reason.
Solution
Sigma bonds are stronger than pi bonds due to the following reasons:
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Overlap Extent: Sigma bonds are formed by the head-on overlapping of atomic orbitals, which creates a strong bond between the two atoms. On the other hand, pi bonds are formed by the lateral or sideways overlapping of atomic orbitals, which is not as effective, resulting in a weaker bond.
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Electron Distribution: In a sigma bond, the electron density is concentrated along the line joining the two bonded atoms, which makes the bond stronger. In a pi bond, the electron density is spread out above and below the plane of the atoms, making the bond weaker.
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Number of Bonds: A single bond is always a sigma bond, while a double bond is composed of one sigma bond and one pi bond, and a triple bond is composed of one sigma bond and two pi bonds. Therefore, sigma bonds are more common and stronger than pi bonds.
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Rotation: Sigma bonds allow free rotation of atoms around the bond axis, while pi bonds restrict this rotation. This makes sigma bonds more stable and stronger than pi bonds.
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