Q1. Which one of the following is the strongest acid?a) CH2ClCOOHb) CH3COOHc) CHCl2COOHd) CCl3COOH
Question
Q1. Which one of the following is the strongest acid?a) CH2ClCOOHb) CH3COOHc) CHCl2COOHd) CCl3COOH
Solution
The strength of an acid is determined by its ability to donate a proton (H+). In the case of carboxylic acids, the more electron-withdrawing groups attached to the molecule, the more stable the resulting anion will be after it donates a proton. This is because electron-withdrawing groups can help to disperse the negative charge, making the anion more stable and therefore making the acid stronger.
Here are the steps to determine the strongest acid:
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Identify the electron-withdrawing groups in each molecule. In this case, the electron-withdrawing groups are the chlorine atoms (Cl).
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Count the number of electron-withdrawing groups in each molecule.
a) CH2ClCOOH has 1 Cl atom.
b) CH3COOH has no Cl atoms.
c) CHCl2COOH has 2 Cl atoms.
d) CCl3COOH has 3 Cl atoms.
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The molecule with the most electron-withdrawing groups will be the strongest acid.
So, the strongest acid among the given options is d) CCl3COOH because it has the most Cl atoms, which are electron-withdrawing groups.
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Which acid is stronger HCl or CH3COOH and why?
Compare acidic strength of following :-(I) CF3COOH (II) CF3CH2COOH(III) NO2–CH2COOHA I > II > III B I > III > II C III > I > II D III > II > I
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