What can be said about a reaction with H = 62.4 kJ/mol and S = 0.145 kJ/(mol·K)?A.It is spontaneous at 500 K.B.It is spontaneous at 298 K.C.It is never spontaneous.D.It is always spontaneous.
Question
What can be said about a reaction with H = 62.4 kJ/mol and S = 0.145 kJ/(mol·K)?A.It is spontaneous at 500 K.B.It is spontaneous at 298 K.C.It is never spontaneous.D.It is always spontaneous.
Solution
The spontaneity of a reaction can be determined using the Gibbs free energy equation:
ΔG = ΔH - TΔS
where: ΔG is the change in Gibbs free energy, ΔH is the change in enthalpy, T is the absolute temperature in Kelvin, ΔS is the change in entropy.
The reaction is spontaneous if ΔG is negative.
Let's calculate ΔG for both temperatures:
- At 500 K: ΔG = 62.4 kJ/mol - 500 K * 0.145 kJ/(mol·K) = 62.4 kJ/mol - 72.5 kJ/mol = -10.1 kJ/mol
Since ΔG is negative, the reaction is spontaneous at 500 K.
- At 298 K: ΔG = 62.4 kJ/mol - 298 K * 0.145 kJ/(mol·K) = 62.4 kJ/mol - 43.21 kJ/mol = 19.19 kJ/mol
Since ΔG is positive, the reaction is not spontaneous at 298 K.
So, the correct answer is A. It is spontaneous at 500 K.
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