Which of the following compounds does not follow the octet rule for electron distribution?Only one correct answerA.PCl5𝑃𝐶𝑙5B.PCl3𝑃𝐶𝑙3C.H2O𝐻2𝑂D.PH3𝑃𝐻3PreviousClearMark for Review & NextNextInstructionsEnglishNot VisitedNot AnsweredAnsweredMarked for ReviewAnswered & Marked for review(will be considered for evaluation)CHEMISTRYSection-ISection-II3132333435363738394041424344454647484950
Question
Which of the following compounds does not follow the octet rule for electron distribution?Only one correct answerA.PCl5𝑃𝐶𝑙5B.PCl3𝑃𝐶𝑙3C.H2O𝐻2𝑂D.PH3𝑃𝐻3PreviousClearMark for Review & NextNextInstructionsEnglishNot VisitedNot AnsweredAnsweredMarked for ReviewAnswered & Marked for review(will be considered for evaluation)CHEMISTRYSection-ISection-II3132333435363738394041424344454647484950
Solution
The compound that does not follow the octet rule for electron distribution is PCl5.
The octet rule states that atoms tend to combine in such a way that they each have eight electrons in their valence shells, giving them the same electronic configuration as a noble gas.
In PCl5 (Phosphorus pentachloride), the central phosphorus atom is surrounded by 10 electrons, not 8. It has 5 valence electrons and it forms 5 bonds with chlorine atoms, so it actually expands its valence shell to hold more than 8 electrons. This is possible because phosphorus is in the third period of the periodic table that have d orbitals available for bonding.
So, the correct answer is A. PCl5.
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