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Which of the following statement is not correct?[Ni(CN)4]−2 and [Ni(CO)4] have the same magnetic moment[NiCl4]−2 and [PtCl4]−2 have different shape.Hybrid state of Co in [Co(Ox)3]−3 is sp3 d2In brown-ring complex [Fe(H2O)5NO]SO4 oxidation state of Fe is +1

Question

Which of the following statement is not correct?[Ni(CN)4]−2 and [Ni(CO)4] have the same magnetic moment[NiCl4]−2 and [PtCl4]−2 have different shape.Hybrid state of Co in [Co(Ox)3]−3 is sp3 d2In brown-ring complex [Fe(H2O)5NO]SO4 oxidation state of Fe is +1

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Solution

The statement that is not correct is: "In brown-ring complex [Fe(H2O)5NO]SO4 oxidation state of Fe is +1".

The oxidation state of Fe in the brown-ring complex [Fe(H2O)5NO]SO4 is actually +3. This is determined by the fact that the overall charge of the complex is neutral, and the sum of the oxidation states of all atoms in the complex must equal the overall charge. The oxidation state of water is 0 and the oxidation state of NO is +1. Therefore, the oxidation state of Fe must be +3 to balance out the -1 charge from the sulfate ion.

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Similar Questions

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