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Acidified potassium dichromate is treated with hydrogen sulphide. In the reaction, the oxidation number of chromiumIncreases from +3 to +6Decreases from +6 to +3Remains unchangedDecreases from +6 to +2

Question

Acidified potassium dichromate is treated with hydrogen sulphide. In the reaction, the oxidation number of chromiumIncreases from +3 to +6Decreases from +6 to +3Remains unchangedDecreases from +6 to +2

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Solution

The oxidation number of chromium decreases from +6 to +3 in this reaction.

Here's the step by step explanation:

  1. Potassium dichromate (K2Cr2O7) is an orange compound where the oxidation state of chromium is +6.

  2. When acidified potassium dichromate is treated with hydrogen sulphide (H2S), the dichromate ion (Cr2O7^2-) is reduced to chromium (III) ion (Cr^3+).

  3. The balanced chemical equation for this reaction is: 3H2S + K2Cr2O7 + 4H2O = 2KHSO4 + 2Cr(OH)3 + 3S

  4. In this reaction, the oxidation state of chromium changes from +6 in the dichromate ion to +3 in the chromium (III) ion.

  5. Therefore, the oxidation number of chromium decreases from +6 to +3 in this reaction.

This problem has been solved

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