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It takes 146./kJmol to break an oxygen-oxygen single bond. Calculate the maximum wavelength of light for which an oxygen-oxygen single bond could be broken by absorbing a single photon.Be sure your answer has the correct number of significant digits.

Question

It takes 146./kJmol to break an oxygen-oxygen single bond. Calculate the maximum wavelength of light for which an oxygen-oxygen single bond could be broken by absorbing a single photon.Be sure your answer has the correct number of significant digits.

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Solution

To solve this problem, we need to use the equation that relates energy, wavelength and Planck's constant:

E = h * c / λ

where: E is the energy, h is Planck's constant (6.626 x 10^-34 Js), c is the speed of light (3.00 x 10^8 m/s), and λ is the wavelength.

We are given the energy in kJ/mol, but we need it in Joules per photon. To convert, we use Avogadro's number (6.022 x 10^23 mol^-1):

E = 146. kJ/mol * (1 mol / 6.022 x 10^23 photons) * (1000 J / 1 kJ) = 2.42 x 10^-19 J/photon

Now we can solve for λ:

λ = h * c / E λ = (6.626 x 10^-34 Js) * (3.00 x 10^8 m/s) / 2.42 x 10^-19 J/photon λ = 8.20 x 10^-7 m

So, the maximum wavelength of light for which an oxygen-oxygen single bond could be broken by absorbing a single photon is 8.20 x 10^-7 m, or 820 nm.

This problem has been solved

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