Hardness of water is estimated simple titration with-Na[EDTA]Na2[EDTA]Na3[EDTA]Na4[EDTA]
Question
Hardness of water is estimated simple titration with-Na[EDTA]Na2[EDTA]Na3[EDTA]Na4[EDTA]
Solution
The hardness of water is typically determined using a titration with Na2[EDTA]. Here are the steps:
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Take a known volume of water sample in a conical flask.
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Add buffer solution to the water sample to maintain the pH. The pH is usually adjusted to about 10.
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Add a few drops of Eriochrome Black T indicator to the water sample. This will turn the solution wine red if hardness is present.
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Titrate this solution with the Na2[EDTA] solution. During the titration, the EDTA molecules sequester the calcium and magnesium ions.
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Continue the titration until the color changes from wine red to blue. This indicates that all the hardness causing ions have reacted with the EDTA.
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Note down the volume of EDTA solution used. This can be used to calculate the hardness of the water.
The formula to calculate hardness is:
Hardness (as CaCO3) in mg/L = (Volume of EDTA solution in mL) x (EDTA concentration in mg/L) x (1000) / (Volume of water sample in mL)
Remember to always run a blank determination alongside your sample to correct for any errors.
Similar Questions
Estimate EDTA method of determining hardness of water
0.50 g of CaCO3 was dissolved in HCl and diluted to 500 ml. 100ml of this solution required 20 ml of EDTA solution for titration. 100 ml of hard water sample required 30 ml of the same EDTA solution for titration. On boiling, titration of 100ml of same water sample required 10 ml of EDTA. Calculate total, temporary and permanent hardness of water. 5M (1 ml of 0.01M EDTA= 1mg of CaCO3)
In an EDTA experiment, the following values are obtained. Calculate the different types of hardness. (EDTA =0.01M) i) 50 ml hard water sample = 25 ml EDTA ii) 50 ml boiled water sample = 14 ml EDTA
250 mL of a water sample on EDTA titration with Eriochrome Black –T consumed 13 mL of 0.022 N EDTA till end point is reached. Calculate the hardness of water ?a.11.44 ppmb.114.4 ppmc.1.14 ppmd.1144 ppm
During the experiment "Estimation of Ca2+ and Mg2+ in a given sample of water by complexometric titration with a standard solution of EDTA," the _______ ions are removed from the given water sample by addition of _______ in the form of __________.Ca, NaOH, CaCO3Mg, NaOH, CaCO3Mg, NH4OH, Ca(OH)2Mg, NaOH, Mg(OH)2
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