Ka of acid decreases on adding NaCl solution
Question
Ka of acid decreases on adding NaCl solution
Solution
The addition of NaCl to an acidic solution does not directly affect the Ka (acid dissociation constant) of the acid. The Ka is a measure of the strength of the acid, and it is a property of the acid itself, not of the solution it is in.
However, adding NaCl can affect the pH of the solution, which might give the impression that the Ka of the acid has changed. Here's how:
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When NaCl is added to the solution, it dissociates into Na+ and Cl- ions.
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The Cl- ions can react with water to form HCl and OH-. This reaction is not favored, and it happens to a very small extent. But even a small amount of OH- can increase the pH of the solution.
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An increase in pH means a decrease in [H+], the concentration of hydrogen ions. Since the Ka of an acid is directly related to [H+], a decrease in [H+] might give the impression that the Ka has decreased.
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However, the actual Ka of the acid has not changed. What has changed is the pH of the solution, and the apparent concentration of H+ ions.
So, in conclusion, adding NaCl to an acidic solution does not decrease the Ka of the acid. It can affect the pH of the solution, but the Ka of the acid itself remains the same.
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