In 30 minutes, a first-order reaction is 50% complete. The time required to complete 87.5 percent of the reaction is ____________________
Question
In 30 minutes, a first-order reaction is 50% complete. The time required to complete 87.5 percent of the reaction is ____________________
Solution
The rate of a first-order reaction is directly proportional to the concentration of one of the reactants. The formula for the rate of a first-order reaction is:
k = ln(2) / t_half
where:
- k is the rate constant
- t_half is the half-life of the reaction, or the time it takes for half of the reactants to be used up
Given that the reaction is 50% complete in 30 minutes, we can say that the half-life of the reaction is 30 minutes. We can use this to find the rate constant:
k = ln(2) / 30 min = 0.0231 min^-1
The time required to complete a certain percentage of a first-order reaction can be found using the formula:
t = ln([A]0 / [A]) / k
where:
- t is the time
- [A]0 is the initial concentration
- [A] is the final concentration
If we want to find the time required to complete 87.5% of the reaction, we can say that the final concentration is 12.5% of the initial concentration (because 100% - 87.5% = 12.5%). Therefore, we can plug these values into the formula:
t = ln(1 / 0.125) / 0.0231 min^-1 = 100 minutes
So, the time required to complete 87.5% of the reaction is approximately 100 minutes.
Similar Questions
99% of a first order reaction, was completed in 32 minute. When will 99.9% of the reaction complete?
Time required for completion of 99.9% of a First order reaction is ________ times of half life (t1/2) of the reaction.
b) Show that time required for a first order reaction to complete 99.9% reaction is approximately 10 times its half life period.
A first order reaction has the rate constant, k=4.6×10−3 s−1. The number of correct statement/s from the following is/are Given: log 3=0.48.A. Reaction completes in 1000 s.B. The reaction has a half-life of 500 s.C. The time required for 10% completion is 25 times the time required for 90% completion.D. The degree of dissociation is equal to (1−e−kt).E. The rate and the rate constant have the same unit.
15. The rate constant for a first order reaction depends on _____________
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