Balance the following redox reaction that takes place in acidic solution: H5IO6(aq) + Cr(s) + → IO3- (aq) + Cr3+ (aq) +
Question
Balance the following redox reaction that takes place in acidic solution: H5IO6(aq) + Cr(s) + → IO3- (aq) + Cr3+ (aq) +
Solution
To balance the redox reaction, we first need to identify the oxidation and reduction half-reactions.
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Identify the oxidation and reduction half-reactions:
- H5IO6(aq) → IO3- (aq) is the reduction half-reaction (Iodine is reduced from +7 to +5)
- Cr(s) → Cr3+ (aq) is the oxidation half-reaction (Chromium is oxidized from 0 to +3)
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Balance the atoms and charges in each half-reaction:
- For the reduction half-reaction:
- Balance the I atoms: H5IO6(aq) → 2IO3- (aq)
- Balance the O atoms by adding H2O: H5IO6(aq) → 2IO3- (aq) + 3H2O(l)
- Balance the H atoms by adding H+: H5IO6(aq) + 10H+ → 2IO3- (aq) + 3H2O(l)
- Balance the charges by adding electrons: H5IO6(aq) + 10H+ + 2e- → 2IO3- (aq) + 3H2O(l)
- For the oxidation half-reaction:
- Balance the Cr atoms: Cr(s) → Cr3+ (aq)
- Balance the charges by adding electrons: Cr(s) → Cr3+ (aq) + 3e-
- For the reduction half-reaction:
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Equalize the number of electrons in the two half-reactions:
- Multiply the reduction half-reaction by 3 and the oxidation half-reaction by 2:
- 3[H5IO6(aq) + 10H+ + 2e- → 2IO3- (aq) + 3H2O(l)]
- 2[Cr(s) → Cr3+ (aq) + 3e-]
- Multiply the reduction half-reaction by 3 and the oxidation half-reaction by 2:
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Add the half-reactions together and simplify:
- 3H5IO6(aq) + 30H+ + 6e- + 2Cr(s) → 6IO3- (aq) + 9H2O(l) + 2Cr3+ (aq) + 6e-
- Cancel out the electrons and simplify the equation to get the final balanced redox reaction:
- 3H5IO6(aq) + 30H+ + 2Cr(s) → 6IO3- (aq) + 9H2O(l) + 2Cr3+ (aq)
So, the balanced redox reaction in acidic solution is: 3H5IO6(aq) + 30H+ + 2Cr(s) → 6IO3- (aq) + 9H2O(l) + 2Cr3+ (aq)
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