Which of the following monosaccharides are epimer pairs?Group of answer choicesα-D-glucopyranose and α-L-glucopyranoseβ-D-gulopyranose and α-D-glucopyranoseα-D-glucopyranose and α-D-glucofuranoseα-D-glucopyranose and α-D-mannopyranoseα-D-galactopyranose and D-galactose in its open chain conformation
Question
Which of the following monosaccharides are epimer pairs?Group of answer choicesα-D-glucopyranose and α-L-glucopyranoseβ-D-gulopyranose and α-D-glucopyranoseα-D-glucopyranose and α-D-glucofuranoseα-D-glucopyranose and α-D-mannopyranoseα-D-galactopyranose and D-galactose in its open chain conformation
Solution
The correct answer is α-D-glucopyranose and α-D-mannopyranose.
Epimers are diastereomers that differ in configuration at only one stereogenic center. In this case, α-D-glucopyranose and α-D-mannopyranose are epimers because they differ only at the C-2 position.
Here's a step-by-step explanation:
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α-D-glucopyranose and α-L-glucopyranose are not epimers, but enantiomers (mirror images of each other).
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β-D-gulopyranose and α-D-glucopyranose are not epimers, but anomers (they differ at the new asymmetric carbon atom formed on ring closure).
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α-D-glucopyranose and α-D-glucofuranose are not epimers, but they are different in their ring size (pyranose is a six-membered ring, and furanose is a five-membered ring).
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α-D-glucopyranose and α-D-mannopyranose are epimers because they differ at the C-2 position.
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α-D-galactopyranose and D-galactose in its open chain conformation are not epimers, but they are different in their ring structure (one is cyclic and the other is linear).
Similar Questions
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Which of the following carbohydrates has a glycosidic linkage?FructofuranoseGlucopyranoseMaltoseβ−D−fructose
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