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Explain SN1 mechanism with example

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Explain SN1 mechanism with example

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Solution

The SN1 mechanism, or unimolecular nucleophilic substitution, is a two-step process that involves the formation of a carbocation intermediate. Here's a step-by-step explanation using the example of the reaction between 2-bromo-2-methylpropane and water:

  1. Step 1: Formation of Carbocation The reaction begins with the departure of the leaving group, which in this case is a bromine atom. This leaves behind a carbocation, which is a positively charged carbon atom. The molecule of 2-bromo-2-methylpropane thus becomes a 2-methylpropyl carbocation.

  2. Step 2: Nucleophilic Attack In the second step, the nucleophile, which is a water molecule in this case, attacks the carbocation. This results in the formation of a new bond and the creation of a new molecule, 2-methylpropan-2-ol.

The SN1 mechanism is called 'unimolecular' because the rate-determining step (the slowest step that determines the rate of the overall reaction) involves only one molecule, which is the substrate (2-bromo-2-methylpropane in this case). The 'N' in SN1 stands for 'nucleophilic', and the '1' indicates that the rate-determining step involves one molecule.

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