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According to the VSEPR theory, what determines the shape of a molecule?

Question

According to the VSEPR theory, what determines the shape of a molecule?

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Solution

According to the Valence Shell Electron Pair Repulsion (VSEPR) theory, the shape of a molecule is determined by the number of valence electron pairs around the central atom of the molecule. Here are the steps to determine the shape:

  1. Identify the central atom in the molecule. This is usually the atom that is single (not bonded to another atom of the same type) and is often the least electronegative.

  2. Determine the number of valence electrons for the central atom. You can find this information on the periodic table.

  3. Determine the number of electron pairs around the central atom. This includes both bonding pairs (pairs of electrons shared between two atoms in a covalent bond) and lone pairs (pairs of electrons that are not involved in bonding).

  4. Use the VSEPR theory to predict the shape of the molecule. The theory states that electron pairs will arrange themselves around the central atom in a way that minimizes repulsion between them. This arrangement determines the shape of the molecule.

For example, if there are two electron pairs around the central atom, they will arrange themselves 180 degrees apart, resulting in a linear shape. If there are three electron pairs, they will arrange themselves in a trigonal planar shape. Four electron pairs will arrange in a tetrahedral shape, and so on. The presence of lone pairs can also affect the shape, as they occupy more space than bonding pairs

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