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The synthesis of urea, commonly used as a fertilizer, is made by reaction of carbon dioxide and ammonia, giving urea (CH4N2O) and water according to the following reaction.CO2(g)  +  2 NH3(g)  →   CH4N2O(s)  +  H2O(l)Data:   compound                   molar mass  (g mol-1)            Carbon dioxide                       44.01            Ammonia                                17.04            Urea                                        60.07            Water                                      18.02Calculate the theoretical yield of urea in grams, starting with 9.66 g ammonia and excess carbon dioxide. Give your answer to three significant figures. Do not include units.

Question

The synthesis of urea, commonly used as a fertilizer, is made by reaction of carbon dioxide and ammonia, giving urea (CH4N2O) and water according to the following reaction.CO2(g)  +  2 NH3(g)  →   CH4N2O(s)  +  H2O(l)Data:   compound                   molar mass  (g mol-1)            Carbon dioxide                       44.01            Ammonia                                17.04            Urea                                        60.07            Water                                      18.02Calculate the theoretical yield of urea in grams, starting with 9.66 g ammonia and excess carbon dioxide. Give your answer to three significant figures. Do not include units.

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Solution

To calculate the theoretical yield of urea, we first need to determine the number of moles of ammonia (NH3) we have.

  1. Calculate the number of moles of ammonia: The molar mass of ammonia is given as 17.04 g/mol. We can use this to find the number of moles in 9.66 g of ammonia.

    Number of moles = mass / molar mass Number of moles of NH3 = 9.66 g / 17.04 g/mol = 0.567 mol

  2. Determine the stoichiometry of the reaction: From the balanced chemical equation, we can see that the reaction consumes ammonia and produces urea in a 2:1 ratio. This means that for every 2 moles of ammonia consumed, 1 mole of urea is produced.

  3. Calculate the number of moles of urea produced: Using the stoichiometry of the reaction, we can calculate the number of moles of urea produced.

    Number of moles of urea = 0.567 mol NH3 * (1 mol CH4N2O / 2 mol NH3) = 0.283 mol CH4N2O

  4. Calculate the mass of urea produced: We can now use the molar mass of urea to find the mass of urea produced.

    Mass = number of moles * molar mass Mass of urea = 0.283 mol * 60.07 g/mol = 17.0 g

So, the theoretical yield of urea is 17.0 g.

This problem has been solved

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