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What do you thinkabout solubility of alkanes in water basedupon non-polar nature of alkanes?

Question

What do you thinkabout solubility of alkanes in water basedupon non-polar nature of alkanes?

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Solution

The solubility of alkanes in water is generally low due to the non-polar nature of alkanes. Here's a step-by-step explanation:

  1. Alkanes are hydrocarbons composed of carbon and hydrogen atoms. They have non-polar covalent bonds, meaning the electrons are shared equally between the atoms.

  2. Water, on the other hand, is a polar molecule. It has a partial positive charge on the hydrogen atoms and a partial negative charge on the oxygen atom.

  3. Like dissolves like, which means that polar substances tend to dissolve in polar solvents, and non-polar substances tend to dissolve in non-polar solvents.

  4. Since alkanes are non-polar and water is polar, there is a significant difference in their polarity. This difference in polarity makes it difficult for alkanes to dissolve in water.

  5. The intermolecular forces between water molecules (hydrogen bonding) are much stronger than the intermolecular forces between water and alkanes (London dispersion forces).

  6. As a result, alkanes are not attracted to water molecules as strongly as water molecules are attracted to each other. This leads to poor solubility of alkanes in water.

  7. However, alkanes are soluble in non-polar solvents such as hexane or benzene, where the intermolecular forces are similar to those in alkanes.

In conclusion, the non-polar nature of alkanes hinders their solubility in water, as water is a polar solvent.

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