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explain the nature of solid state; z explain the properties of solids in terms of packing of particles and intermolecular attractions; z differentiate between crystalline and amorphous solids; z explain the melting point of a solid; z classify the crystalline solids according to the forces operating between the constituent particles; z define the terms crystal lattice and unit cell; z describe different types of two dimensional and three dimensional unit cells; z explain different types of packing in the solids; z define coordination number;

Question

explain the nature of solid state; z explain the properties of solids in terms of packing of particles and intermolecular attractions; z differentiate between crystalline and amorphous solids; z explain the melting point of a solid; z classify the crystalline solids according to the forces operating between the constituent particles; z define the terms crystal lattice and unit cell; z describe different types of two dimensional and three dimensional unit cells; z explain different types of packing in the solids; z define coordination number;

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Solution

  1. Nature of Solid State: Solids are characterized by having a definite shape and volume. The particles in a solid are closely packed, usually in a regular pattern. The particles vibrate about their mean positions and cannot move from one place to another.

  2. Properties of Solids: Solids are generally hard and rigid. They have high densities and do not compress easily. They have a fixed melting and boiling point. These properties are due to the close packing of particles and strong intermolecular attractions.

  3. Crystalline vs Amorphous Solids: Crystalline solids have a regular and repeating pattern of particles, giving them a definite shape. They have sharp melting points. Amorphous solids, on the other hand, do not have a regular arrangement of particles and do not have a sharp melting point.

  4. Melting Point of a Solid: The melting point of a solid is the temperature at which it changes state from solid to liquid. It is the point at which the kinetic energy of the particles is enough to overcome the intermolecular forces holding the particles together.

  5. Classification of Crystalline Solids: Crystalline solids can be classified based on the forces operating between the constituent particles. These include ionic solids (forces between ions), molecular solids (forces between molecules), covalent or network solids (covalent bonds), and metallic solids (metallic bonds).

  6. Crystal Lattice and Unit Cell: A crystal lattice is the regular arrangement of particles in a crystalline solid. A unit cell is the smallest repeating unit of the lattice that shows the symmetry of the entire lattice.

  7. Types of Unit Cells: Two-dimensional unit cells include square, rectangular, and hexagonal. Three-dimensional unit cells include cubic, tetragonal, orthorhombic, rhombohedral, hexagonal, monoclinic, and triclinic.

  8. Types of Packing in Solids: There are two types of packing in solids - close packing and open packing. Close packing is further divided into hexagonal close packing and cubic close packing.

  9. Coordination Number: The coordination number of a particle in a crystal is the number of nearest neighbors it has. For example, in a cubic close-packed structure, each particle has a coordination number of 12.

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