Carbon sitting in the octahedral void in FCC-iron is an example of……………a.Frankel defectb.Interstitial impurityc.Substitutional impurityd.Vacancy defect
Question
Carbon sitting in the octahedral void in FCC-iron is an example of……………a.Frankel defectb.Interstitial impurityc.Substitutional impurityd.Vacancy defect
Solution
The answer is b. Interstitial impurity.
Here's why:
In a crystal lattice, atoms or ions occupy specific positions. However, there are also voids or empty spaces where an atom or ion could fit. These are known as interstitial sites.
When an atom from a different element occupies one of these interstitial sites, it is known as an interstitial impurity. This is the case with carbon in FCC-iron. The carbon atom is small enough to fit into the octahedral voids in the iron crystal lattice, making it an interstitial impurity.
Frankel and vacancy defects are types of point defects that involve vacancies or empty lattice sites, while substitutional impurities involve an atom from a different element replacing an atom in the host crystal lattice. These are not the case with carbon in FCC-iron.
Similar Questions
Carbon sitting in the octahedral void in FCC-iron is an example of……………
The defect that occurs due to a displacement of an ion is known as……………a.Vacancy defectb.Frankel defectc.Schottky defectd.Impurity defect
In a solid lattice, the cation has left a lattice site and is located at an interstitial position, the lattice defect is :Interstitial defectValency defectFrenkel defectSchottky defect
We noted in Section 12.5 (Figure 12.20) that in FeO (wüstite), the iron ions can exist in both Fe2+ and Fe3+ states. The number of each of these ion types depends on temperature and the ambient oxygen pressure. Furthermore, we also noted that in order to retain electroneutrality, one Fe2+ vacancy will be created for every two Fe3+ ions that are formed; consequently, in order to reflect the existence of these vacancies the formula for wüstite is often represented as Fe(1 – x)O, where x is some small fraction less than unity. In this nonstoichiometric Fe(1 – x)O material, conduction is electronic, and, in fact, it behaves as a p-type semiconductor—that is, the Fe3+ ions act as electron acceptors, and it is relatively easy to excite an electron from the valence band into an Fe3+ acceptor state, with the formation of a hole. Determine the electrical conductivity of a specimen of wüstite that has a hole mobility of 1.0 × 10–5 m2/V.s and for which the value of x is 0.040. Assume that the acceptor states are saturated (i.e., one hole exists for every Fe3+ ion). Wüstite has the sodium chloride crystal structure with a unit cell edge length of 0.437 nm.
Number of tetrahedral voids in the FCC unit cell is
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