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The presence of a bromine atom in a molecule will produce a mass spectrum with an (M+2)+• peak that is approximately equal to the intensity of the molecular ion peak becauseSelect answer from the options belowthe 79Br isotope has a higher natural abundance than 81Br isotope.molecules with the 79Br and 81Br isotopes tend to fragment easily.the 79Br and 81Br isotopes have almost equal natural abundance.the 81Br isotope has a higher natural abundance than 79Br isotope.

Question

The presence of a bromine atom in a molecule will produce a mass spectrum with an (M+2)+• peak that is approximately equal to the intensity of the molecular ion peak becauseSelect answer from the options belowthe 79Br isotope has a higher natural abundance than 81Br isotope.molecules with the 79Br and 81Br isotopes tend to fragment easily.the 79Br and 81Br isotopes have almost equal natural abundance.the 81Br isotope has a higher natural abundance than 79Br isotope.

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Solution

The correct answer is "the 79Br and 81Br isotopes have almost equal natural abundance."

This is because bromine has two stable isotopes, 79Br and 81Br, which occur in nearly equal amounts in nature (50.69% and 49.31% respectively). When a molecule containing bromine is ionized in a mass spectrometer, it will produce molecular ions of both isotopes. This results in two peaks of approximately equal intensity in the mass spectrum, the (M)+• peak and the (M+2)+• peak.

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