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1.0 mole of a weak acid HA was dissolved in 2.0 L of solution. After the system had come to equilibrium, the concentration of HA was found to be 0.34 M. Calculate Ka for HA.

Question

1.0 mole of a weak acid HA was dissolved in 2.0 L of solution. After the system had come to equilibrium, the concentration of HA was found to be 0.34 M. Calculate Ka for HA.

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Solution

To solve this problem, we first need to understand the dissociation of a weak acid. A weak acid HA dissociates in water as follows:

HA ⇌ H+ + A-

At the beginning, we have 1.0 mole of HA in a 2.0 L solution, so the initial concentration of HA is 1.0 mol / 2.0 L = 0.5 M.

At equilibrium, the concentration of HA is given as 0.34 M. This means that 0.5 M - 0.34 M = 0.16 M of HA has dissociated.

Since for every HA that dissociates we get one H+ and one A-, the concentrations of H+ and A- at equilibrium are also 0.16 M.

The equilibrium constant Ka for the weak acid is then given by:

Ka = [H+][A-] / [HA]

Substituting the equilibrium concentrations into this expression gives:

Ka = (0.16 M)(0.16 M) / (0.34 M) = 0.0075

So, the Ka for the weak acid HA is 0.0075.

This problem has been solved

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f Ka of a weak acid HA is 10–5 then Kh for NaA will be

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